A kinetic model involving oxidation and volatilization in SiC-B4C-xAl2O3 ceramics system

In this paper, a new kinetic model considering both oxidation and volatilization kinetics is established and applied to analyze the oxidation of SiC-B₄C-xAl₂O₃ ceramics and other systems in various oxidation conditions. The effects of diffusion area and volume changes during the oxidation process are considered in this model. The physical meaning of each parameter in this model is explicit and simple. According to this model, the diffusion coefficient of species and the corresponding diffusion activation energy are easily available. The practicability of this model is well verified by the experimental data of SiC-B₄C-xAl₂O₃ and other systems oxidized under different conditions. In addition, the practice shows that the model is applicable not only to the systems where oxidation and volatilization coexist, but also to the system where only oxidation plays a major role. We hope the model proposed in this work can be used in other materials with more complex environments.     

A novel method of shrimp blanching by CO2 heat pump: Quality,energy, and economy analysis

To reduce the energy consumption of the shrimp blanching process and improve the economic value of the blanched product, a transcritical CO₂ heat pump blanching system (THPB system) was designed in this paper. The trends of astaxanthin were investigated at atmospheric pressure near boiling temperature, combined with the color and structural properties of shrimp samples, and the optimal blanching times of 270 s and 240 s were obtained at 90°C and 95°C, respectively. In contrast to the fuel blanching system (FB system) at 100°C, the annual standard coal consumption of the THPB system with 90°C blanching is decreased by 79%, and the annual operating cost can be saved by CNY 63,800, with a payback period of about 3.13 years.Industrial relevanceBlanching is one of the effective ways to prolong the shelf life of shrimp. However, the research on the blanching time and temperature of shrimp is not comprehensive. In addition, the traditional fuel blanching process has high energy consumption and pollution, and can no longer meet the quality requirements of the modern food processing industry. Heat pump has been shown to have better performance in food drying, but it is less used in blanching. The information presented in this study may provide other insights into food processing.     

Hydrogen storage performance of methyl-substituted mesoporous silica with tailored textural characteristics

Journal of Porous Materials - The present study reports a systematic analysis of morphology and hydrogen sorption capacity of mesoporous organic-inorganic silica prepared by varying the silica...     

Optimizing the stability and electrical transport properties of CeNbO4+δ-based oxide ceramics by regulating oxygen ion content

CeNbO_4+δ ceramics have attracted extensive research interest because of their unique mixed ion-electron transport characteristics and interesting structure-functional characteristics caused by the difference in oxygen ion content. Although the change of oxygen ion content brings rich redox properties, it also causes serious crystal transformation and abnormal electrical transport properties. In order to obtain stable structure and excellent electrical transport properties, the directional regulation of the oxygen ion content has been realized through introducing Al₂O₃ and high temperature aging. After 600 h of aging at 1073 K, the prepared composite ceramics not only obtain a stable structure without crystal transformation, but also show good negative temperature coefficient (NTC) thermistor characteristics in the temperature range of 473 K–1273 K, in which the linear fitting maximum Pearson's r of the relationship between lnρ and 1000/T can reach 99.97%. The proposed method provides a new thought for the design and application of high-temperature electronic ceramics.     

Evolution of core–rim structures and phase transformations in infra-red transmitting Y-α-SiAlON ceramics

Core–rim structures were observed as common features in Y-α-SiAlON ceramics hot-pressed between 1550?1950 °C. We found most dopants were taken into α’-rims, and a transition layer grown first on α-cores from liquid-phase over-saturated with metal solutes. Elongated β’-grain were formed as minor phase with α’- or AlN-cores thus only after the α’ matrix had consumed up all Y solutes, revealing that the α’ → β’ transformation is controlled by the transient liquid-phase and similar defects and dangling bonds could be detected in both SiAlON phases by cathodoluminescence. Quantitative assessment of Y_m/3Si_12?(m+n)Al_m+nO_nN_16?n demonstrates the multiphase evolution, initiated by over-saturation of Y solutes at low temperatures thus retaining α-phase as cores to lower the infra-red transmittance, dictated by homogenization of Al solutes at higher temperature. The elimination of those phase boundaries leads to better dopant and sintering design for achieving transparent and high-performance SiAlON ceramics.     

Investigation on NBTI-induced dynamic variability in nanoscale CMOS devices: Modeling,experimental evidence,and impact on circuits

With the downscaling of CMOS devices, dynamic variability induced by negative bias temperature instability (NBTI) has become a critical issue. In addition to the time-dependent device-to-device variation (DDV) of NBTI degradation, the cycle-to-cycle variation (CCV) originated from random trap occupation is found non-negligible and should be added into the total dynamic variation. This paper summarizes our recent studies on NBTI-induced dynamic variability, focusing on the CCV effect, with more details on the statistical modeling, circuit reliability simulation methodologies and experimental results. By adding the random trap occupation into consideration, a statistical model for total dynamic variation (DDV + CCV) is proposed. The effective occupancy probability p_eff is introduced as a key parameter for modeling and circuit reliability simulation. With the statistical trap response (STR) method and modified on-the-fly method, the proposed model is validated by the experimental evidence under both DC and AC NBTI. According to the model and experimental results, circuit reliability simulation framework is proposed for both long-term quasi-static and short-term transient performance evaluation with the additional impact of CCV. Two representative digital circuit units, ring oscillator (RO) and SRAM cell, are simulated under different conditions, indicating it necessary to consider the evident influence of the CCV in accurate circuit reliability evaluation. The results are helpful for the reliability/variability-aware circuit design in nanoscale technology.     

Laser impact welding: Investigation on microstructure and mechanical properties of molybdenum-copper welding joint

Due to their excellent properties, molybdenum and copper are widely used in the electronics industry. However, the welding of molybdenum and copper is difficult, which limits their application prospects in the field of microelectronics devices. This paper describes a novel method for Mo/Cu welding in micro devices: laser impact welding (LIW). The experimental results found that welding improved with the increase of laser energy. The springback and interface wave in the welding area were observed by optical microscope and scanning electron microscope (SEM)and the results showed that the shapes of the interface wave were flat and zigzag. Energy dispersive spectroscopy (EDS) showed little or no diffusion of elements at the welding interface. Tensile shear test results of the welded specimens showed that there were two kinds of failure forms: solder joint failure and solder joint edge failure. The nano-hardness of the materials in the welding area increased compared with the raw materials.     

Gas-assisted exfoliation of boron nitride nanosheets enhancing adsorption performance

A gas exfoliation strategy for controllable preparation of boron nitride (BN) nanosheets with few-layered structure were reported. The green exfoliation process provides the BN nanosheets remarkable increment of adsorption capacities to organic contaminants, which is ascribed to better exposure of active sites originating from the larger surface area and thinner layer. Moreover, the prepared BN also exhibits outstanding recyclability.